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红外光谱和改性木材因人工光照而产生的颜色变化。

FTIR and color change of the modified wood as a result of artificial light irradiation.

机构信息

"Petru Poni" Institute of Macromolecular Chemistry, 41A Gr. Ghica-Voda Alley, Iasi 700487, Romania.

出版信息

J Photochem Photobiol B. 2010 Jun 1;99(3):144-9. doi: 10.1016/j.jphotobiol.2010.03.010. Epub 2010 Mar 27.


DOI:10.1016/j.jphotobiol.2010.03.010
PMID:20392648
Abstract

The effect of UV-visible light irradiation on the changes in color and chemical composition of the surfaces of Abies alba L. (fir, a softwood), non-modified and chemically modified, was studied. Chemical modification of the wood was performed by reaction with succinic anhydride in xylene at different concentration values. The wood samples were irradiated in air using a rotative device equipped with a middle pressure mercury lamp. Analysis of the color changes in wood surfaces during photo-degradation was carried out by measuring CIELAB parameters. Fourier transform infrared spectroscopy was used to study chemical changes caused by light irradiation. Irradiation modified physical and chemical characteristics of wood surfaces and resulted in rapid color changes, degradation of lignin and increased content of chromophoric groups on the wood surfaces. Color changes (DeltaE(ab)) correlate well with degradation of lignin.

摘要

研究了紫外可见光照射对未改性和化学改性的白皮松(软木)表面颜色和化学成分变化的影响。木材的化学改性是通过在二甲苯中与琥珀酸酐反应在不同浓度值下进行的。使用配备中压汞灯的旋转装置在空气中对木材样品进行照射。通过测量 CIELAB 参数来分析光降解过程中木材表面颜色的变化。傅里叶变换红外光谱用于研究光照引起的化学变化。辐照改变了木材表面的物理和化学特性,导致颜色迅速变化、木质素降解和木材表面生色团含量增加。颜色变化(ΔE(ab))与木质素降解密切相关。

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