Gifu Prefectural Human Life Technology Research Institute, Takayama 506-0058, Japan.
J Photochem Photobiol B. 2010 Dec 2;101(3):210-4. doi: 10.1016/j.jphotobiol.2010.07.005. Epub 2010 Jul 25.
This paper deals with the photobleaching of acetylated wood. The acetylated spruce wood was irradiated by artificial sunlight emitted from xenon lamp with covering several kinds of band-pass filter. The lightness (L()) of acetylated wood increased with integral irradiance. The chroma (ΔC()) decreased by light-irradiation with wavelength from 430nm to 500nm. However, the light-irradiation including ultraviolet ray region made it decrease after increase with integral irradiance. The visible light made hue angle (h°) increase, however, the ultraviolet ray made it decrease. The lignin degradation and the production of carbonyl groups were observed by light-irradiation including ultraviolet ray. However, no remarkable changes in IR spectra were observed by visible light-irradiation. Photobleaching of acetylated wood was caused by mainly visible light without modifying the IR spectra of lignin.
本文研究了乙酰化木材的光漂白作用。采用氙灯光源,通过覆盖几种带通滤光片对乙酰化云杉木材进行人工光照。随着积分辐照度的增加,乙酰化木材的明度(L())增加。在 430nm 到 500nm 的波长范围内,光致漂白会使色度(ΔC())降低。然而,包含紫外线区域的光致漂白会使色度在积分辐照度增加后再次降低。可见光会使色调角(h°)增加,而紫外线则会使其降低。光致漂白包括紫外线照射会导致木质素降解和羰基的生成。然而,可见光照射并没有观察到 IR 光谱的显著变化。乙酰化木材的光漂白主要是由可见光引起的,而不会改变木质素的 IR 光谱。