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阳离子和阴离子表面活性剂在有机聚合物树脂 Lewatit VPOC 1064 MD PH 上的吸附。

Adsorption of cationic and anionic surfactants onto organic polymer resin Lewatit VPOC 1064 MD PH.

机构信息

Department of Environmental Engineering, Faculty of Engineering, Istanbul University, 34320 Avcilar, Istanbul, Turkey.

出版信息

Environ Geochem Health. 2010 Aug;32(4):267-73. doi: 10.1007/s10653-010-9297-7. Epub 2010 Apr 16.

Abstract

The adsorption of a cationic (CTAB, cetyl trimethylammonium bromide) and an anionic surfactant (SLES, sodium dodecylethersulfate) from aqueous solution onto organic polymer resin (Lewatit VPOC 1064 MD PH) was studied. A series of batch experiments were performed to determine the sorption isotherms of surfactants to organic polymer resin. The experimental studies were analyzed by Langmuir and Freundlich isotherms. Furthermore, the isotherm parameters, average percentage errors (epsilon) of model data, and separation factor (R (L)) were calculated. Other factors influencing the adsorption capacity (contact time, adsorbent amount, and initial surfactant concentration) were also discussed. The experimental data fitted very well to the Langmuir equilibrium model in the studied concentration range. The calculated R (L) values showed that the adsorption of both surfactants were favorable. Among the surfactants, CTAB showed higher adsorption capacity onto organic polymer resin compared to SLES (Q (0) = 250 and 34.36 mg g(-1), respectively).

摘要

研究了阳离子(十六烷基三甲基溴化铵,CTAB)和阴离子表面活性剂(十二烷基醚硫酸钠,SLES)从水溶液中吸附到有机聚合物树脂(Lewatit VPOC 1064 MD PH)上的情况。进行了一系列批实验,以确定表面活性剂对有机聚合物树脂的吸附等温线。通过 Langmuir 和 Freundlich 等温线对实验研究进行了分析。此外,还计算了等温线参数、模型数据的平均百分比误差(epsilon)和分离因子(R(L))。还讨论了影响吸附能力的其他因素(接触时间、吸附剂用量和初始表面活性剂浓度)。实验数据在研究的浓度范围内非常符合 Langmuir 平衡模型。计算的 R(L)值表明,两种表面活性剂的吸附都是有利的。在这些表面活性剂中,CTAB 对有机聚合物树脂的吸附能力高于 SLES(Q(0)分别为 250 和 34.36mg/g)。

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