Drummond D L
Appl Opt. 1982 Dec 1;21(23):4331-4. doi: 10.1364/AO.21.004331.
The index of refraction of hydrogen fluoride has been measured from 2.5 to 2.9 microm with a wavelength resolution of 40 A. Fringe shifts were measured using an incandescent light, a Mach Zehnder interferometer, and a quarter-meter monochromator. The hydrogen fluoride pressure varied from 20 to 120 T. Higher pressures would not be tolerated because of the presence of HF dimers. From 2.5 to 2.7 microm, the dispersion curve is dominated by the resonant dispersion of the P-branch absorption lines. From 2.8 to 2.9 microm, n - 1 is nearly constant at a value of (1.27 +/- 0.05) x 10(-4) for standard temperature and pressure. Theoretical modeling of the dispersion curve has produced the following values for HF A coefficients: P(l) = 168 +/- 20 sec(-1), P(2) = 120 +/- 20 sec(-1), P(3) = 100 +/- 20 sec(-1).
已在2.5至2.9微米范围内测量了氟化氢的折射率,波长分辨率为40埃。使用白炽灯、马赫曾德尔干涉仪和四分之一米单色仪测量条纹移动。氟化氢压力在20至120T之间变化。由于存在HF二聚体,无法承受更高的压力。在2.5至2.7微米范围内,色散曲线由P支吸收线的共振色散主导。在2.8至2.9微米范围内,对于标准温度和压力,n - 1几乎恒定在(1.27 +/- 0.05)×10^(-4)的值。色散曲线的理论建模得出了以下HF A系数值:P(1)=168 +/- 20秒^(-1),P(2)=120 +/- 20秒^(-1),P(3)=100 +/- 20秒^(-1)。