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从动物骨骼制备羟基磷灰石。

Preparation of hydroxyapatite from animal bones.

作者信息

Sobczak Agnieszka, Kowalski Zygmunt, Wzorek Zbigniew

机构信息

Institute of Inorganic Chemistry and Technology, Cracow University of Technology, Cracow, Poland.

出版信息

Acta Bioeng Biomech. 2009;11(4):23-8.

Abstract

This paper presents the method of obtaining hydroxyapatite from animal bones. Bone sludge and calcined products were characterized by X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). Calcium concentration was determined with titration, and phosphorus--spectrophotometrically. Making use of the AAS and ICP methods the content of microelements was determined. In all the products, hydroxyapatite was the only crystalline phase indicated. The FT-IR spectra confirmed that calcination removed the total of organic substances. Calcium and phosphorus contents were 38% and 18%, respectively, which corresponded to the Ca/P molar ratio of nonstoichiometric hydroxyapatite. The specific surfaces of products were measured by BET method. The volume of micro- and mesopores was determined.

摘要

本文介绍了从动物骨骼中获取羟基磷灰石的方法。通过X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)和扫描电子显微镜(SEM)对骨泥和煅烧产物进行了表征。通过滴定法测定钙浓度,用分光光度法测定磷浓度。利用原子吸收光谱法(AAS)和电感耦合等离子体法(ICP)测定微量元素含量。在所有产物中,羟基磷灰石是唯一显示出的晶相。FT-IR光谱证实煅烧去除了所有有机物质。钙和磷的含量分别为38%和18%,这与非化学计量羟基磷灰石的Ca/P摩尔比相对应。通过BET法测量产物的比表面积。测定了微孔和介孔的体积。

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