金（I）催化的 N-氨苯基丙炔基丙二酸盐形成二氢喹啉和吲哚。
Gold(I)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates.
机构信息
Laboratoire de Synthèse Organique, UMR 7652 CNRS/Ecole Polytechnique, Ecole Polytechnique, 91128 Palaiseau, France.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):218-20. doi: 10.1039/c0cc00033g. Epub 2010 Apr 21.
PMID:20411208
Abstract
The use of [XPhosAu(NCMe)]SbF(6) in nitromethane at 100 °C allows the rapid and efficient formation of variously substituted dihydroquinolines, which can be subsequently converted into indoles by a rare photochemical rearrangement.
摘要
在 100°C 的硝基甲烷中使用 [XPhosAu(NCMe)]SbF(6) 可以快速有效地形成各种取代的二氢喹啉，这些二氢喹啉随后可以通过罕见的光化学重排转化为吲哚。
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