Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK.
Chem Commun (Camb). 2010 Jun 14;46(22):3991-3. doi: 10.1039/c0cc00157k. Epub 2010 Apr 28.
The formation of radicals in the gas phase oxidation of cyclohexane over metal oxides was studied using spin trapping and EPR spectroscopy; the results confirmed that during the catalytic initiation, the oxygen responsible for the radicals formation originates from the lattice of the metal oxide.
使用自旋捕获和电子顺磁共振波谱法研究了金属氧化物气相氧化环己烷中自由基的形成;结果证实,在催化引发过程中,形成自由基的氧来源于金属氧化物的晶格。