Organic Chemistry Section, National Institute for Interdisciplinary Science and Technology (CSIR), Trivandrum 695 019, India.
Org Lett. 2010 Jun 4;12(11):2653-5. doi: 10.1021/ol1008697.
A facile NHC-mediated reaction of aromatic aldehydes with carbon dioxide leading to carboxylic acids is described. The present protocol is mechanistically important, and it can serve as a tool for the sequestration of carbon dioxide.
描述了一种芳醛与二氧化碳在 NHC 作用下的简便反应,生成羧酸。本方案具有重要的机理意义,可作为二氧化碳捕集的工具。