Department of Chemistry, University of Pennsylvania, Pennsylvania 19104, United States.
Org Lett. 2011 May 6;13(9):2422-5. doi: 10.1021/ol2006538. Epub 2011 Apr 12.
NHC-catalyzed oxidations using carbon dioxide as the stoichiometric oxidant have been carefully investigated. These studies support a secondary role of CO(2) in suppressing side reactions and exogenous oxygen as the actual oxidant.
NHC 催化氧化反应使用二氧化碳作为计量氧化剂进行了仔细研究。这些研究支持了 CO(2) 在抑制副反应和外源性氧作为实际氧化剂方面的次要作用。