Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China.
Chem Soc Rev. 2009 Dec;38(12):3419-34. doi: 10.1039/b901649j. Epub 2009 Sep 2.
Over the past decade, supramolecular compounds with organometallic Ir, Rh, Ru based half-sandwich complexes have received considerable attention as materials with a variety of potential applications. The major emphasis of this tutorial review lies on the self-assembly of such organometallic half-sandwich molecular rectangles, prisms and cages with half-sandwich corners and two different rigid bifunctional ligands using an approach of stepwise construction. Synthetic methods and the structural and functional properties of the target complexes are discussed in detail.
在过去的十年中，基于有机金属 Ir、Rh、Ru 的半夹心配合物的超分子化合物作为具有多种潜在应用的材料受到了相当大的关注。本综述的主要重点在于使用逐步构建的方法，自组装具有半夹心角和两个不同刚性双功能配体的这种有机金属半夹心分子矩形、棱柱体和笼。详细讨论了目标配合物的合成方法和结构与功能性质。
