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AgOC(CF3)3:一种用于制备过渡金属-NHC-卡宾配合物的替代且高效的试剂。

AgOC(CF(3))(3): an alternative and efficient reagent for preparing transition metal-NHC-carbene complexes.

机构信息

Université de Lyon, Institut de Chimie de Lyon, C2P2-Equipe COMS (UMR 5265 CNRS-CPE Lyon-Université de Lyon 1), CPE Lyon, 43 Bd du 11 Novembre 1918, F-69616, Villeurbanne Cedex, France.

出版信息

Dalton Trans. 2009 Sep 21(35):6956-9. doi: 10.1039/b900136k. Epub 2009 Jun 8.

Abstract

AgOC(CF(3))(3), a soluble source, was found to be a convenient reagent for the one-pot preparation of Ag-NHC and M-NHC complexes starting from imidazoliums (M = Au, Ir, Pd and Ru).

摘要

AgOC(CF3)3,一种可溶性的源,被发现是一种方便的试剂,用于从咪唑鎓(M = Au、Ir、Pd 和 Ru)一锅法制备 Ag-NHC 和 M-NHC 配合物。

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