Institut für Anorganische Chemie der Universität Göttingen, Tammannstrasse 4, D 37077 Göttingen, Germany.
Inorg Chem. 2011 Sep 5;50(17):8502-8. doi: 10.1021/ic201096c. Epub 2011 Jul 22.
Reactions of N-heterocyclic carbene stabilized dichlorosilylene IPr·SiCl(2) (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with (η(5)-C(5)H(5))V(CO)(4), (η(5)-C(5)H(5))Co(CO)(2), and Fe(2)(CO)(9) afford dichlorosilylene complexes IPr·SiCl(2)·V(CO)(3)(η(5)-C(5)H(5)) (2), IPr·SiCl(2)·Co(CO)(η(5)-C(5)H(5)) (3), and IPr·SiCl(2)·Fe(CO)(4) (4), respectively. Complexes 2-4 are stable under an inert atmosphere, are soluble in common organic solvents, and have been characterized by elemental analysis and multinuclear ((1)H, (13)C, and (29)Si) NMR spectroscopy. Molecular structures of 2-4 have been determined by single crystal X-ray crystallographic studies and refined with nonspherical scattering factors.
N-杂环卡宾稳定的二氯硅烯 IPr·SiCl(2)（1）（IPr=1,3-双（2,6-二异丙基苯基）咪唑-2-亚基）与（η(5)-C(5)H(5))V(CO)(4)、（η(5)-C(5)H(5))Co(CO)(2)和 Fe(2)(CO)(9)反应，分别得到二氯硅烯配合物 IPr·SiCl(2)·V(CO)(3)(η(5)-C(5)H(5))（2）、IPr·SiCl(2)·Co(CO)(η(5)-C(5)H(5))（3）和 IPr·SiCl(2)·Fe(CO)(4)（4）。配合物 2-4 在惰性气氛下稳定，可溶于常见有机溶剂，并通过元素分析和多核（（1）H、（13）C 和（29）Si）NMR 光谱进行了表征。通过单晶 X 射线晶体学研究确定了 2-4 的分子结构，并使用非球形散射因子进行了精修。
