Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing100871, PR China.
Chem Commun (Camb). 2010 Apr 21;46(15):2554-6. doi: 10.1039/b925917a. Epub 2010 Mar 12.
Mononuclear spin-crossover complex Fe(II)(L)(2) x CH(3)OH (1 x CH(3)OH) and its desolvated product 1 exhibit abrupt spin transitions around room temperature. 1 also shows a light induced excited spin state trapping (LIESST) effect and a light induced thermal hysteresis (LITH) phenomenon at low temperature.
单核自旋交叉配合物 Fe(II)(L)(2) x CH(3)OH(1 x CH(3)OH)及其去溶剂化产物 1 在室温附近表现出急剧的自旋转变。1 还在低温下表现出光致激发态自旋捕获(LIESST)效应和光致热滞后(LITH)现象。