Energy and Environment Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99352, USA.
Dalton Trans. 2010 Feb 21;39(7):1692-4. doi: 10.1039/b921118g. Epub 2009 Nov 9.
Micro and mesoporous metal-organic frameworks were synthesized using a single tetrahedral building block and their catalytic properties towards alkylation of toluene and biphenyl showed high selectivity for the para oriented product using these porous materials.
使用单个四面体结构单元合成了微孔和介孔金属有机骨架,并用这些多孔材料对甲苯和联苯的烷基化反应进行了催化性能研究,结果表明,这些多孔材料对对位产物具有很高的选择性。