高产的弱配位碳硼烷阴离子 C 衍生化。
High yield C-derivatization of weakly coordinating carborane anions.
机构信息
Center for S and P Block Chemistry, Department of Chemistry, University of California, Riverside, California 92651, USA.
出版信息
Inorg Chem. 2010 Jun 7;49(11):4726-8. doi: 10.1021/ic100053u.
Abstract
Unlike the "parent" carborane anion CHB(11)H(11)(-), halogenated carborane anions such as CHB(11)H(5)Br(6)(-) can be readily C-functionalized in high yield and purity, enhancing their utility as weakly coordinating anions.
摘要
不同于“母体” carborane 阴离子 CHB(11)H(11)(-)，卤素取代的 carborane 阴离子，如 CHB(11)H(5)Br(6)(-)，可以高产率、高纯度地进行 C 官能化，从而增强它们作为弱配位阴离子的实用性。
相似文献
1
High yield C-derivatization of weakly coordinating carborane anions.高产的弱配位碳硼烷阴离子 C 衍生化。
Inorg Chem. 2010 Jun 7;49(11):4726-8. doi: 10.1021/ic100053u.
2
Double addition of H2 to transition metal-borane complexes: a 'hydride shuttle' process between boron and transition metal centres.双氢加成过渡金属硼烷配合物：硼和过渡金属中心之间的“氢化物穿梭”过程。
Chem Commun (Camb). 2011 Jan 7;47(1):484-6. doi: 10.1039/c0cc02245d. Epub 2010 Oct 11.
3
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.H(+)、CH(3)(+) 和 R(3)Si(+) 卡硼烷试剂：当三氟甲磺酸酯失败时。
Acc Chem Res. 2010 Jan 19;43(1):121-8. doi: 10.1021/ar900159e.
4
Synthesis, structure, and stability of adducts between phosphide and amide anions and the Lewis acids borane, tris(pentafluorophenyl)borane, and tris(pentafluorophenyl)alane.膦化物和酰胺阴离子与路易斯酸硼烷、三（五氟苯基）硼烷和三（五氟苯基）铝烷加合物的合成、结构和稳定性。
Inorg Chem. 2009 Dec 7;48(23):11474-82. doi: 10.1021/ic901799q.
5
Palladium catalysed enantioselective phosphination reactions using secondary phosphine-boranes and aryl iodide.使用仲膦硼烷和芳基碘化物的钯催化对映选择性膦化反应。
Chem Commun (Camb). 2005 May 14(18):2393-5. doi: 10.1039/b501078k. Epub 2005 Mar 15.
6
Ruthenium complexes with cooperative PNP ligands: bifunctional catalysts for the dehydrogenation of ammonia-borane.具有协同PNP配体的钌配合物：用于氨硼烷脱氢的双功能催化剂。
Angew Chem Int Ed Engl. 2009;48(5):905-7. doi: 10.1002/anie.200805108.
7
BF3-mediated additions of organolithiums to ketimines: X-ray crystal structures of BF3-ketimine complexes.三氟化硼介导的有机锂对酮亚胺的加成反应：三氟化硼-酮亚胺配合物的X射线晶体结构
J Org Chem. 2005 Mar 18;70(6):2335-7. doi: 10.1021/jo0480895.
8
Borylcyanocuprate in a one-pot carboboration by a sequential reaction with an electron-deficient alkyne and an organic carbon electrophile.硼氰基铜酸盐通过与缺电子炔烃和有机碳亲电试剂的顺序反应进行一锅法碳硼化反应。
Angew Chem Int Ed Engl. 2011 Jan 24;50(4):920-3. doi: 10.1002/anie.201005667. Epub 2010 Dec 22.
9
Palladium-catalyzed regioselective intramolecular coupling of o-carborane with aromatics via direct cage B-H activation.钯催化邻位碳硼烷与芳烃的区域选择性分子内环化反应：通过直接笼状 B-H 活化。
J Am Chem Soc. 2015 Mar 18;137(10):3502-5. doi: 10.1021/jacs.5b01169. Epub 2015 Mar 10.
10
Alkylating agents stronger than alkyl triflates.比三氟甲磺酸烷基酯更强的烷基化剂。
J Am Chem Soc. 2004 Oct 6;126(39):12451-7. doi: 10.1021/ja047357d.
引用本文的文献
1
Noncatalyzed Intramolecular B-N and B-O Cross-Coupling of "Inert" Carboranes Lead to the Formation of an Unusual Oxoborane, via Reversible Cluster C-B Bond Scission.“惰性”碳硼烷的非催化分子内B-N和B-O交叉偶联通过可逆的簇C-B键断裂导致形成一种不寻常的氧硼烷。
J Am Chem Soc. 2025 May 28;147(21):17764-17771. doi: 10.1021/jacs.5c01106. Epub 2025 May 13.
本文引用的文献
1
Salts of the 1-cyanocarba-closo-dodecaborate anions [1-NC-closo-1-CB11X11]- (X = H, F, Cl, Br, I).1-氰基-closo-十二硼酸盐阴离子的盐 [1-NC-closo-1-CB11X11]-（X = H、F、Cl、Br、I）。
Dalton Trans. 2010 Mar 14;39(10):2708-16. doi: 10.1039/b922720b. Epub 2010 Feb 4.
2
Gas-phase Brønsted superacidity of some derivatives of monocarba-closo-borates: a computational study.一些单碳笼硼酸盐衍生物的气相 Brønsted 超酸：计算研究。
J Phys Chem A. 2009 Nov 19;113(46):12972-8. doi: 10.1021/jp905449k.
3
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.H(+)、CH(3)(+) 和 R(3)Si(+) 卡硼烷试剂：当三氟甲磺酸酯失败时。
Acc Chem Res. 2010 Jan 19;43(1):121-8. doi: 10.1021/ar900159e.
4
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.使用硅鎓-碳硼烷催化剂对全氟烷基进行加氢脱氟反应。
Science. 2008 Aug 29;321(5893):1188-90. doi: 10.1126/science.1159979.
5
The sixteen CB(11)H(n)Me(12-n)(-) anions with fivefold substitution symmetry: anodic oxidation and electronic structure.
J Am Chem Soc. 2007 Oct 31;129(43):12960-80. doi: 10.1021/ja066247z. Epub 2007 Oct 5.
6
[Me3Si][R-CB11F11]--synthesis and properties.
Angew Chem Int Ed Engl. 2007;46(33):6346-9. doi: 10.1002/anie.200701136.
7
Chemistry of the carba-closo-dodecaborate(-) anion, CB(11)H(12)(-).碳硼烷-闭式-十二硼酸盐（-）阴离子CB(11)H(12)(-)的化学性质
Chem Rev. 2006 Dec;106(12):5208-49. doi: 10.1021/cr050548u.
8
Noncoordinating anions--fact or fiction? A survey of likely candidates.非配位阴离子——事实还是虚构？对可能候选物的调查。
Angew Chem Int Ed Engl. 2004 Apr 13;43(16):2066-90. doi: 10.1002/anie.200300620.
9
A copolymerized dodecacarborane anion as covalently attached cation exchanger in ion-selective sensors.一种共聚十二碳硼烷阴离子作为离子选择性传感器中通过共价连接的阳离子交换剂。
Anal Chem. 2003 Nov 1;75(21):6002-10. doi: 10.1021/ac034447c.
10
Molecular Rods. 1. Simple Axial Rods.分子棒。1. 简单轴向棒。
Chem Rev. 1999 Jul 14;99(7):1863-1934. doi: 10.1021/cr970070x.
Zotero 插件