Center for Advanced Optoelectronic Functional Materials Research, Key Laboratory of UV Light-Emitting Materials and Technology of Ministry of Education, Department of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun 130024, People's Republic of China.
J Colloid Interface Sci. 2010 Aug 1;348(1):37-42. doi: 10.1016/j.jcis.2010.04.035. Epub 2010 Apr 18.
A novel zinc phthalocyanine (ZnPc) hierarchical nanostructure with hollow interior space has been successfully obtained by a facile ethylene glycol solvent-thermal synthetic route. The as-obtained products were characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), IR spectrum, UV-vis spectrum, Brunauer-Emmett-Teller analysis and contact angle measurement. It was indicated that the ZnPc micro-rectangular tubes with hollow interior space were built from densely nanosheets with a thickness of about 20 nm. The obtained ZnPc showed high visible photocatalytic property to degrade rhodamine B (RB), which could be ascribed to the contribution of hierarchical nanostructure, high crystallinity and super-hydrophobic property.
一种新型的具有中空内部空间的锌酞菁（ZnPc）分级纳米结构通过简便的乙二醇溶剂热合成路线成功获得。通过场发射扫描电子显微镜（FE-SEM）、透射电子显微镜（TEM）、X 射线衍射（XRD）、红外光谱（IR）、紫外-可见光谱（UV-vis）、BET 分析和接触角测量对所得到的产物进行了表征。结果表明，具有中空内部空间的 ZnPc 微矩形管由厚度约为 20nm 的密集纳米片构建而成。所获得的 ZnPc 对罗丹明 B（RB）的可见光光催化降解具有很高的性能，这可归因于分级纳米结构、高结晶度和超疏水性的贡献。
