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交叉轴同步流通式盘管行星离心机(XLL型)。二、关于固定相保留中流体动力学机制的推测。

Cross-axis synchronous flow-through coil planet centrifuge (type XLL). II. Speculation on the hydrodynamic mechanism in stationary phase retention.

作者信息

Ito Y

机构信息

Laboratory of Biophysical Chemistry, National Heart, Lung, and Blood Institute, National Institutes of Health, Bethesda, MD 20892.

出版信息

J Chromatogr. 1991 Jan 18;538(1):67-80. doi: 10.1016/s0021-9673(01)91622-x.

Abstract

The hydrodynamic mechanism involved in the retention of stationary phase in the present x-axis coil planet centrifuge system is discussed. A statistical treatment of the retention data disclosed important clues such as the effect of the inward-outward elution mode, the close correlation between the planetary motion and the head-tail elution mode, and the superior retention capacity of the left-handed coils. The combined effects of the radial and lateral centrifugal force field derived from the mathematical analysis of acceleration acting on the coil provide an explanation for the phenomena.

摘要

讨论了当前x轴螺旋行星离心机系统中固定相保留所涉及的流体动力学机制。对保留数据的统计处理揭示了重要线索,如内外洗脱模式的影响、行星运动与头尾洗脱模式之间的密切相关性以及左手螺旋线圈的卓越保留能力。通过对作用于螺旋线圈的加速度进行数学分析得出的径向和横向离心力场的综合作用,为这些现象提供了解释。

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