Department of Chemistry and Chemical Biology, McMaster University, 1280 Main St. W., Hamilton ON, CanadaL8S 4M1.
Chem Commun (Camb). 2010 Jul 21;46(27):4988-90. doi: 10.1039/c0cc00369g. Epub 2010 May 28.
The Piers-Rubinsztajn reaction, involving B(C(6)F(5))(3)-catalyzed siloxane formation from hydrosilanes + alkoxysilanes, is tolerant of a wide variety of functional groups, and provides a generic strategy for the preparation of structurally complex functional silicones.
皮尔斯-鲁宾斯坦反应涉及 B(C(6)F(5))(3)催化的硅氧烷从氢硅烷+烷氧基硅烷形成，对各种官能团具有耐受性，并为制备结构复杂的功能性硅酮提供了一种通用策略。
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