Organic Chemistry Division-I, Indian Institute of Chemical Technology, Council of Scientific and Industrial Research, Hyderabad, India.
Bioorg Med Chem Lett. 2010 Jun 15;20(12):3814-7. doi: 10.1016/j.bmcl.2010.04.030. Epub 2010 Apr 21.
The racemic total synthesis of elegansidiol, farnesiferol B, and farnesiferol D has been obtained following a Diels-Alder approach. Gillman addition, cross metathesis reaction are the other key steps involved in the target synthesis.
采用 Diels-Alder 方法获得了 elegansidiol、farnesiferol B 和 farnesiferol D 的外消旋全合成。Gillman 加成、交叉复分解反应是目标合成中涉及的其他关键步骤。