Nguyen Minh T, Holliday Bradley J
Department of Chemistry, The University of Texas at Austin, 105 E. 24th St., Stop A5300, Austin, TX 78712-0165, USA.
Chem Commun (Camb). 2015 May 21;51(41):8610-3. doi: 10.1039/c5cc01719j.
Conducting polymers of a Schiff-base ligand and the corresponding oxo-vanadium(IV) complex have been synthesized, characterized, and studied. The metal-free ligand polymer allows for direct comparison between the properties of the ligand polymer and corresponding conducting metallopolymer. The role of the metal centers in the conducting metallopolymer is elucidated unambiguously.
席夫碱配体与相应的氧钒（IV）配合物的导电聚合物已被合成、表征和研究。无金属配体聚合物使得能够直接比较配体聚合物和相应导电金属聚合物的性质。明确阐明了金属中心在导电金属聚合物中的作用。
