Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Avenue SE, Minneapolis, Minnesota 55455, USA.
ACS Nano. 2010 Aug 24;4(8):4388-95. doi: 10.1021/nn100966s.
Printing electronic components on plastic foils with functional liquid inks is an attractive approach for achieving flexible and low-cost circuitry for applications such as bendable displays and large-area sensors. The challenges for printed electronics, however, include characteristically slow switching frequencies and associated high supply voltages, which together impede widespread application. Combining printable high-capacitance dielectrics with printable high-mobility semiconductors could potentially solve these problems. Here we demonstrate fast, flexible digital circuits based on semiconducting carbon nanotube (CNT) networks and high-capacitance ion gel gate dielectrics, which were patterned by jet printing of liquid inks. Ion gel-gated CNT thin-film transistors (TFTs) with 50 microm channel lengths display ambipolar transport with electron and hole mobilities >20 cm(2)/V.s; these devices form the basis of printed inverters, NAND gates, and ring oscillators on both polyimide and SiO(2) substrates. Five-stage ring oscillators achieve frequencies >2 kHz at supply voltages of 2.5 V, corresponding to stage delay times of 50 micros. This performance represents a substantial improvement for printed circuitry fabricated from functional liquid inks.
用功能液体油墨在塑料箔上打印电子元件是一种很有吸引力的方法,可以实现灵活和低成本的电路,适用于可弯曲显示器和大面积传感器等应用。然而,印刷电子学面临的挑战包括典型的缓慢开关频率和相关的高电源电压,这两者共同阻碍了其广泛应用。将高电容介电材料与高迁移率半导体结合在一起,可能会解决这些问题。在这里,我们展示了基于半导体碳纳米管(CNT)网络和高电容离子凝胶栅介电材料的快速、灵活的数字电路,这些电路是通过喷墨打印液体油墨来进行图案化的。具有 50 微米沟道长度的离子凝胶门控 CNT 薄膜晶体管(TFT)具有>20 cm2/V·s 的电子和空穴迁移率,表现出双极性传输特性;这些器件构成了在聚酰亚胺和 SiO2 衬底上打印的逆变器、与非门和环形振荡器的基础。五阶环形振荡器在 2.5 V 的电源电压下实现了>2 kHz 的频率,对应的阶段延迟时间为 50 微秒。对于用功能液体油墨制造的印刷电路来说,这种性能有了很大的提高。