Department of Applied Chemistry, Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Org Lett. 2010 Aug 6;12(15):3390-3. doi: 10.1021/ol1012108.
The regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals was accomplished. Various alkenes such as ethylene, 1-alkenes, and cyclic alkenes were applicable for this reaction system. The alkylindium product from the carboindation of cyclohexene revealed an anti addition mechanism.
三溴化铟和烯酮硅缩醛对简单烯烃的区域选择性碳氢加成反应已完成。该反应体系适用于各种烯烃，如乙烯、1-烯烃和环烯烃。环己烯碳氢加成反应生成的烷基铟产物显示出反式加成机理。
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