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200nm 厚掺钐非晶态 AlN 薄膜的强红光 Catho 和光致发光。

Intense Red Catho- and Photoluminescence from 200 nm Thick Samarium Doped Amorphous AlN Thin Films.

出版信息

Nanoscale Res Lett. 2009 Apr 25;4(7):748-52. doi: 10.1007/s11671-009-9309-7.

DOI:10.1007/s11671-009-9309-7
PMID:20596367
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2894235/
Abstract

Samarium (Sm) doped aluminum nitride (AlN) thin films are deposited on silicon (100) substrates at 77 K by rf magnetron sputtering method. Thick films of 200 nm are grown at 100-200 watts RF power and 5-8 m Torr nitrogen, using a metal target of Al with Sm. X-ray diffraction results show that films are amorphous. Cathodoluminescence (CL) studies are performed and four peaks are observed in Sm at 564, 600, 648, and 707 nm as a result of (4)G(5/2) --> (6)H(5/2), (4)G(5/2) --> (6)H(7/2), (4)G(5/2) --> (6)H(9/2), and (4)G(5/2) --> (6)H(11/2) transitions. Photoluminescence (PL) provides dominant peaks at 600 and 707 nm while CL gives the intense peaks at 600 nm and 648 nm, respectively. Films are thermally activated at 1,200 K for half an hour in a nitrogen atmosphere. Thermal activation enhances the intensity of luminescence.

摘要

掺钐(Sm)氮化铝(AlN)薄膜采用射频磁控溅射法在 77K 下沉积在硅(100)衬底上。在 100-200 瓦射频功率和 5-8 毫托氮气下,使用含有 Sm 的 Al 金属靶材生长出 200nm 厚的薄膜。X 射线衍射结果表明,薄膜为非晶态。进行了阴极发光(CL)研究,观察到 Sm 在 564、600、648 和 707nm 处有四个峰,这是由于(4)G(5/2) --> (6)H(5/2)、(4)G(5/2) --> (6)H(7/2)、(4)G(5/2) --> (6)H(9/2) 和 (4)G(5/2) --> (6)H(11/2)跃迁。光致发光(PL)在 600nm 和 707nm 处提供主要峰,而 CL 在 600nm 和 648nm 处分别给出强烈的峰。薄膜在氮气气氛中于 1200K 下热激活半小时。热激活增强了发光强度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ece/3243413/e373559e9ffe/1556-276X-4-748-2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ece/3243413/ea260f068eee/1556-276X-4-748-1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ece/3243413/e373559e9ffe/1556-276X-4-748-2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ece/3243413/ea260f068eee/1556-276X-4-748-1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ece/3243413/e373559e9ffe/1556-276X-4-748-2.jpg

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本文引用的文献

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