Florida Solar Energy Center, 1679 Clearlake Road, Cocoa, FL 32922, USA.
Bioresour Technol. 2010 Nov;101(21):8424-8. doi: 10.1016/j.biortech.2010.05.089. Epub 2010 Jul 3.
The aim of this work was to conduct the experimental study of pyrolysis of fast-growing aquatic biomass -Lemna minor (commonly known as duckweed) with the emphasis on the characterization of main products of pyrolysis. The yields of pyrolysis gas, pyrolytic oil (bio-oil) and char were determined as a function of pyrolysis temperature and the sweep gas (Ar) flow rate. Thermogravimetric/differential thermogravimetric (TG/DTG) analyses of duckweed samples in inert (helium gas) and oxidative (air) atmosphere revealed differences in the TG/DTG patterns obtained for duckweed and typical plant biomass. The bio-oil samples produced by duckweed pyrolysis at different reaction conditions were analyzed using GC-MS technique. It was found that pyrolysis temperature had minor effect on the bio-oil product slate, but exerted major influence on the relative quantities of the individual pyrolysis products obtained. While, the residence time of the pyrolysis vapors had negligible effect on the yield and composition of the duckweed pyrolysis products.
本工作的目的是对快速生长的水生生物质——浮萍(俗称浮萍)进行热解实验研究,重点是对热解主要产物的特性进行研究。热解气体、热解油(生物油)和焦炭的产率随热解温度和扫气(Ar)流量的变化而变化。浮萍样品在惰性(氦气)和氧化性(空气)气氛下的热重/差热重(TG/DTG)分析表明,浮萍和典型植物生物质的 TG/DTG 图谱存在差异。采用 GC-MS 技术对不同反应条件下浮萍热解得到的生物油样品进行了分析。结果表明,热解温度对生物油产物的种类影响较小,但对所得到的各个热解产物的相对数量影响较大。而热解蒸汽的停留时间对浮萍热解产物的产率和组成几乎没有影响。