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[活性污泥及污泥改良土壤中多氯二苯并对二噁英/多氯二苯并呋喃污染水平的研究]

[Research of PCDD/Fs pollution level in activated sludge and sludge amended soils].

作者信息

Shi Ye-hong, Chen Zuo-shen, Shen Yang

机构信息

Dioxins Laboratory, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China.

出版信息

Huan Jing Ke Xue. 2010 May;31(5):1287-92.

Abstract

The pollution level of PCDD/Fs of activated sludge in the different processing stages on Beijing Daxing Sludge Composting Plant and pollution level in the neighboring sludge amended soils were studied, and the pollution level was compared with the surrounding background soils. The concentration levels of PCDD/Fs of activated sludge samples in the different treatment stages were 3118.31-3617.36 pg/g, and the TEQ was 26.19-35.81 pg/g, which ranked in middle and lower level in worldwide studies. The concentration of PCDD/Fs of sludge amended soils and background soil samples were 55.05-72.07 pg/g, 8.69-18.06 pg/g respectively, and the TEQ were 1.20-2.64 pg/g, 0.28-0.39 pg/g. The agriculture application of sewage sludge increased the concentration level of PCDD/Fs and their isomers in sludge amended soils, and the total quantity increase ratio was 3.0-8.3. The concentration of PCDD/Fs in sewage sludge amended soils displayed positive correlation with application rates. The concentration distribution pattern of 17 kinds isomers of PCDD/Fs in sewage sludge amended soil was similar with activated sludge, and was very different from background soils. The activated sludge was the main source of PCDD/Fs in sludge amended soils. This study explored the affection of pollution levels of PCDD/Fs in the farmland soils because of the application of activated sludge, and revealed the sources of pollution and contamination patterns of PCDD/Fs in sewage sludge amended soils.

摘要

对北京大兴污泥堆肥厂不同处理阶段活性污泥中多氯二苯并二恶英/多氯二苯并呋喃(PCDD/Fs)的污染水平以及周边污泥改良土壤中的污染水平进行了研究,并将污染水平与周边背景土壤进行了比较。不同处理阶段活性污泥样品中PCDD/Fs的浓度水平为3118.31 - 3617.36 pg/g,毒性当量(TEQ)为26.19 - 35.81 pg/g,在全球研究中处于中低水平。污泥改良土壤和背景土壤样品中PCDD/Fs的浓度分别为55.05 - 72.07 pg/g、8.69 - 18.06 pg/g,TEQ分别为1.20 - 2.64 pg/g、0.28 - 0.39 pg/g。污水污泥的农业应用增加了污泥改良土壤中PCDD/Fs及其异构体的浓度水平,总量增加比例为3.0 - 8.3。污水污泥改良土壤中PCDD/Fs的浓度与施用量呈正相关。污水污泥改良土壤中PCDD/Fs的17种异构体的浓度分布模式与活性污泥相似,与背景土壤差异很大。活性污泥是污泥改良土壤中PCDD/Fs的主要来源。本研究探讨了活性污泥施用对农田土壤中PCDD/Fs污染水平的影响,揭示了污水污泥改良土壤中PCDD/Fs的污染来源和污染模式。

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