Pd(OAc)(2)/HPMoV/O(2)体系催化苯与丙烯腈直接氧化偶联制备肉桂腈。
Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system.
机构信息
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan.
出版信息
Org Biomol Chem. 2010 Sep 21;8(18):4071-3. doi: 10.1039/c0ob00176g. Epub 2010 Jul 23.
PMID:20652185
Abstract
A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)(2)/HPMoV/O(2) catalyst system via the direct C-H bond activation of benzenes using molecular oxygen as a terminal oxidant.
摘要
通过使用 Pd(OAc)(2)/HPMoV/O(2)催化剂体系，以分子氧作为末端氧化剂，通过苯的直接 C-H 键活化，成功地从丙烯腈直接合成出肉桂腈。
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