Key Laboratory for Green Chemical Process of Ministry of Education, School of Materials Science and Engineering, Wuhan Institute of Technology, State Key Laboratory of Coordination Chemistry, Nanjing University, 430073, Wuhan, People's Republic of China.
Nanoscale Res Lett. 2009 Nov 28;5(2):433-7. doi: 10.1007/s11671-009-9501-9.
Polpyrrole (PPy)/Ag nanocomposites were successfully synthesized at the interface of water and ionic liquid by one-step UV-induced polymerization. Highly dispersed PPy/Ag nanoparticles were obtained by controlling the experimental conditions. The results of Fourier-transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy revealed that the UV-induced interface polymerization leaded to the formation of PPy incorporating silver nanoparticles. It was also found that the electrical conductivity of PPy/Ag nanocomposite was about 100 times higher than that of pure PPy.
聚吡咯(PPy)/Ag 纳米复合材料通过一步 UV 诱导聚合在水和离子液体的界面成功合成。通过控制实验条件,获得了高度分散的 PPy/Ag 纳米粒子。傅里叶变换红外光谱、X 射线衍射、透射电子显微镜和 X 射线光电子能谱的结果表明,UV 诱导的界面聚合导致了含有银纳米粒子的 PPy 的形成。还发现 PPy/Ag 纳米复合材料的电导率比纯 PPy 高约 100 倍。