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SYNTHESIS OF SPIROBORATE ESTERS FROM 1,2-AMINOALCOHOLS, ETHYLENE GLYCOL AND TRIISOPROPYL BORATE: PREPARATION OF (S)-1-(1,3,2-DIOXABOROLAN-2-YLOXY)-3-METHYL-1,1-DIPHENYLBUTAN-2-AMINE.

作者信息

Stepanenko Viatcheslav, Huang Kun, Ortiz-Marciales Margarita, Hughes David

出版信息

Organic Synth. 2010;87:26.

PMID:20694191
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915795/
Abstract
摘要

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Spiroborate esters in the borane-mediated asymmetric synthesis of pyridyl and related heterocyclic alcohols.硼烷介导的吡啶基及相关杂环醇不对称合成中的螺硼酸酯
Tetrahedron Asymmetry. 2007 Nov 26;18(23):2738-2745. doi: 10.1016/j.tetasy.2007.10.044.
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手性环氧化物通过螺环硼酸酯酯催化的 2-卤代酮的硼烷还原：在光学纯 1,2-羟基醚和 1,2-叠氮醇合成中的应用。
J Org Chem. 2011 Mar 18;76(6):1883-6. doi: 10.1021/jo102294j. Epub 2011 Feb 4.
Novel dimethoxy(aminoalkoxy)borate derived from (S)-diphenylprolinol as highly efficient catalyst for the enantioselective boron-mediated reduction of prochiral ketones.
源自(S)-二苯基脯氨醇的新型二甲氧基(氨基烷氧基)硼酸盐作为前手性酮对映选择性硼介导还原反应的高效催化剂。
Tetrahedron Lett. 2009 Mar 4;50(9):995-998. doi: 10.1016/j.tetlet.2008.12.061.
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Catalytic enantioselective Diels--Alder reactions: methods, mechanistic fundamentals, pathways, and applications.催化对映选择性狄尔斯-阿尔德反应：方法、机理基础、途径及应用
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A practical and efficient route for the highly enantioselective synthesis of mexiletine analogues and novel beta-thiophenoxy and pyridyl ethers.一种实用且高效的路线，用于美西律类似物以及新型β-噻吩氧基和吡啶基醚的高对映选择性合成。
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7
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Nitrogen-containing ligands for asymmetric homogeneous and heterogeneous catalysis.
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