高区域和对映选择性催化不对称氢化α-取代苯乙烯衍生物。
Highly regio- and enantioselective catalytic asymmetric hydroboration of α-substituted styrenyl derivatives.
机构信息
University of Geneva, Organic Chemistry Department, Quai Ernest Ansermet 30, 1211-Geneva, Switzerland.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):298-300. doi: 10.1039/c0cc01547d. Epub 2010 Oct 14.
PMID:20697639
Abstract
The catalytic asymmetric hydroboration of a variety of 1,1-disubstituted olefins has been achieved with excellent yields, perfect regioselectivity and in some cases, high levels of enantioselectivity using readily accessible iridium catalyst.
摘要
使用易得的铱催化剂，实现了多种 1,1-取代烯烃的催化不对称硼氢化反应，具有优异的产率、完美的区域选择性，在某些情况下还具有高对映选择性。
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