硅上甲基的催化官能化：铱催化的甲基氯硅烷的 C(sp3)-H 硼化反应。
Catalytic functionalization of methyl group on silicon: iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes.
机构信息
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
出版信息
J Am Chem Soc. 2012 Oct 24;134(42):17416-9. doi: 10.1021/ja307956w. Epub 2012 Oct 12.
PMID:23043232
Abstract
A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 °C, giving (borylmethyl)chlorosilanes selectively.
摘要
在铱催化下，甲基氯硅烷与频哪醇硼酸酯在环己烷中于 80°C 发生 C-H 硼化反应，甲基选择性地转化为 (硼代甲基)氯硅烷。
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