Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan.
Chem Commun (Camb). 2013 Sep 4;49(68):7546-8. doi: 10.1039/c3cc44149k.
Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.
铱（I）催化 1-环烯基羧酸衍生物的 C-H 硼化反应，与双（频哪醇）二硼反应，以优异的产率得到各种带有官能团的烯基硼酸酯。该反应也可用于一锅法硼化/Suzuki-Miyaura 交叉偶联反应。
