从α-氯代甘氨酸酯合成 5-氨基-噁唑-4-羧酸酯。
Synthesis of 5-amino-oxazole-4-carboxylates from alpha-chloroglycinates.
机构信息
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada.
出版信息
Org Lett. 2010 Sep 3;12(17):3942-5. doi: 10.1021/ol101704r.
PMID:20698488
Abstract
Aluminum-based Lewis acids are effective promoters of the condensation of alpha-chloroglycinates with isonitriles or with cyanide ion, leading to the formation of 5-amino-oxazoles.
摘要
铝基路易斯酸是促进α-氯代甘氨酸与异腈或氰离子缩合形成 5-氨基噁唑的有效催化剂。
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