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热等离子体相互作用:金纳米粒子光热疗效的新视角。

Hot plasmonic interactions: a new look at the photothermal efficacy of gold nanoparticles.

机构信息

Joint American-Belarussian Laboratory for Fundamental and Biomedical Nanophotonics, A. V. Lykov Heat & Mass Transfer Institute, 15 P. Brovka St., Minsk, 220072, Belarus.

出版信息

Phys Chem Chem Phys. 2010 Oct 14;12(38):12237-44. doi: 10.1039/c0cp00499e. Epub 2010 Aug 16.

Abstract

The photothermal (PT) outputs of individual gold nanoparticles (NP) were compared at room (cold) and high transient (hot) temperatures. High temperatures were induced in NPs by a single 0.5 ns laser pulse. All NPs with near-infrared plasmon resonances (rods, shells and bi-pyramids) exhibited a significant decrease in their photothermal output at the resonant wavelengths under high temperature, while non-resonant excitation of the same NPs provided several times higher PT efficacy of the hot NPs. This "inversion" of the PT efficacy of hot plasmonic NPs near their plasmon resonances might have been caused by damping of their resonances due to heating and surface melting. Therefore, photothermal output of plasmonic nanoparticles significantly depends upon their thermal state including the shift in excitation wavelength in hot nanoparticles. In particular, NPs with near-infrared resonances perform several times more efficiently at non-resonant excitation wavelengths rather than at the resonant ones.

摘要

比较了单个金纳米粒子(NP)在室温(冷)和高温瞬态(热)下的光热(PT)输出。通过单个 0.5ns 激光脉冲在 NPs 中诱导高温。所有具有近红外等离子体共振(棒、壳和双金字塔)的 NPs 在高温下在共振波长下表现出光热输出的显著降低,而相同 NPs 的非共振激发提供了热 NPs 的光热功效的几倍提高。这种近等离子体共振的热等离子体 NPs 的光热功效的“反转”可能是由于加热和表面熔化导致的共振阻尼引起的。因此,等离子体纳米粒子的光热输出显著取决于它们的热状态,包括热纳米粒子中激发波长的移动。特别是,具有近红外共振的 NPs 在非共振激发波长下比在共振波长下的效率高几倍。

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