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1

Catalytic asymmetric protonation of alpha-amino acid-derived ketene disilyl acetals using P-spiro diaminodioxaphosphonium barfates as chiral proton.手性 P-螺环二氨基二氧膦巴福特盐作为手性质子对α-氨基酸衍生的偕二硅基缩酮的催化不对称质子化。

J Am Chem Soc. 2010 Sep 8;132(35):12240-2. doi: 10.1021/ja105945z.

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Enantioselective protonation of α-hetero carboxylic acid-derived ketene disilyl acetals under chiral ionic Brønsted acid catalysis.在手性离子布朗斯特酸催化下α-杂羧酸衍生的烯酮二硅基缩醛的对映选择性质子化反应。

Chem Commun (Camb). 2014 Nov 14;50(88):13489-91. doi: 10.1039/c4cc06081d.

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A new silicon lewis acid for highly enantioselective mannich reactions of aliphatic ketone-derived hydrazones.一种用于脂肪族酮衍生腙的高对映选择性曼尼希反应的新型硅路易斯酸。

J Am Chem Soc. 2008 May 28;130(21):6676-7. doi: 10.1021/ja800830h. Epub 2008 Apr 30.

4

Gallium tribromide catalyzed coupling reaction of alkenyl ethers with ketene silyl acetals.三溴化镓催化的烯基醚与乙烯基硅基缩醛的偶联反应。

Angew Chem Int Ed Engl. 2012 Aug 6;51(32):8073-6. doi: 10.1002/anie.201203778. Epub 2012 Jul 2.

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Catalytic enantioselective construction of all-carbon quaternary stereocenters: synthetic and mechanistic studies of the C-acylation of silyl ketene acetals.全碳季碳立体中心的催化对映选择性构建：硅基烯酮缩醛C-酰化反应的合成与机理研究

J Am Chem Soc. 2005 Apr 20;127(15):5604-7. doi: 10.1021/ja043832w.

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Synthesis of α,α-disubstituted α-amino esters: nucleophilic addition to iminium salts generated from amino ketene silyl acetals.α,α-二取代-α-氨基酯的合成：氨基烯酮硅基缩醛生成的亚胺盐的亲核加成。

J Org Chem. 2011 Dec 2;76(23):9670-7. doi: 10.1021/jo201692x. Epub 2011 Oct 31.

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Catalytic, enantioselective alkylation of alpha-imino esters: the synthesis of nonnatural alpha-amino acid derivatives.α-亚氨基酯的催化对映选择性烷基化反应：非天然α-氨基酸衍生物的合成

J Am Chem Soc. 2002 Jan 9;124(1):67-77. doi: 10.1021/ja016838j.

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Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates.铱催化的手性烯丙基取代反应，用硅基烯酮缩醛作为酯烯醇盐。

Angew Chem Int Ed Engl. 2017 Jul 17;56(30):8887-8891. doi: 10.1002/anie.201704354. Epub 2017 Jun 27.

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Catalytic enantioselective synthesis of quaternary stereocenters via intermolecular C-acylation of silyl ketene acetals: dual activation of the electrophile and the nucleophile.通过硅基烯酮缩醛的分子间C-酰化反应催化对映选择性合成季碳立体中心：亲电试剂和亲核试剂的双重活化

J Am Chem Soc. 2003 Apr 9;125(14):4050-1. doi: 10.1021/ja028554k.

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Catalytic asymmetric protonation of lithium enolates using amino acid derivatives as chiral proton sources.使用氨基酸衍生物作为手性质子源对烯醇锂进行催化不对称质子化反应。

Org Lett. 2006 Apr 13;8(8):1721-4. doi: 10.1021/ol0603007.

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手性 P-螺环二氨基二氧膦巴福特盐作为手性质子对α-氨基酸衍生的偕二硅基缩酮的催化不对称质子化。

Catalytic asymmetric protonation of alpha-amino acid-derived ketene disilyl acetals using P-spiro diaminodioxaphosphonium barfates as chiral proton.

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