TAPC 促进的硫化物氧化和亚砜脱氧。
TAPC-promoted oxidation of sulfides and deoxygenation of sulfoxides.
机构信息
Department of Chemistry, Razi University, Kermanshah 67149-67346, Iran.
出版信息
J Org Chem. 2010 Sep 17;75(18):6208-13. doi: 10.1021/jo1011784.
PMID:20726549
Abstract
1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride (TAPC) was found to be an efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent yields, short reaction time, easy and quick isolation of the products, solvent-free process, and excellent chemoselectivity are the main advantages of this procedure.
摘要
1,3,5-三氮唑-2,4,6-三磷腈-2,2,4,4,6,6-六氯（TAPC）被发现是一种有效的促进剂，可用于氧化硫化物和脱氧化亚砜。该方法具有产率高、反应时间短、产物易于快速分离、无溶剂过程以及优异的化学选择性等主要优点。
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