Wang Xiaoyu, Wang Pan, Dong Zihao, Dong Zhengping, Ma Zongyan, Jiang Jian, Li Rong, Ma Jiantai
College of Chemistry and Chemical Engineering, Lanzhou University, 730000 Lanzhou, People's Republic of China.
Nanoscale Res Lett. 2010 Jun 17;5(9):1468-1473. doi: 10.1007/s11671-010-9663-5.
An inorganic-organic hybrid fluorescence chemosensor (DA/SBA-15) was prepared by covalent immobilization of a dansylamide derivative into the channels of mesoporous silica material SBA-15 via (3-aminopropyl)triethoxysilane (APTES) groups. The primary hexagonally ordered mesoporous structure of SBA-15 was preserved after the grafting procedure. Fluorescence characterization shows that the obtained inorganic-organic hybrid composite is highly selective and sensitive to Hg(2+) detection, suggesting the possibility for real-time qualitative or quantitative detection of Hg(2+) and the convenience for potential application in toxicology and environmental science.
通过将丹磺酰胺衍生物经(3-氨丙基)三乙氧基硅烷(APTES)基团共价固定到介孔二氧化硅材料SBA-15的孔道中,制备了一种无机-有机杂化荧光化学传感器(DA/SBA-15)。接枝过程后,SBA-15的原始六方有序介孔结构得以保留。荧光表征表明,所获得的无机-有机杂化复合材料对Hg(2+)检测具有高度选择性和灵敏性,这表明对Hg(2+)进行实时定性或定量检测具有可能性,并且在毒理学和环境科学中的潜在应用具有便利性。