• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

功能环芳烷:用于光学生物分子识别的有前途的主体。

Functional cyclophanes: promising hosts for optical biomolecular recognition.

机构信息

Photosciences and Photonics, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (NIIST), CSIR, Trivandrum 695 019, India.

出版信息

Chem Soc Rev. 2010 Nov;39(11):4158-68. doi: 10.1039/b920032k. Epub 2010 Aug 20.

DOI:10.1039/b920032k
PMID:20730143
Abstract

Cyclophanes possess a defined cavity size and are efficient in encapsulating and stabilising guest molecules inside the cavity through various non-covalent interactions. This unique property of the cyclophanes has been widely exploited for the development of selective probes for a variety of guest molecules. The present tutorial review highlights the use of various interesting functionalised cyclophane architectures for the sensitive and selective optical recognition of important biomolecules.

摘要

环芳烷具有确定的空腔大小,并通过各种非共价相互作用有效地将客体分子封装和稳定在空腔内。环芳烷的这种独特性质已被广泛用于开发各种客体分子的选择性探针。本综述重点介绍了各种有趣的功能化环芳烷结构在重要生物分子的灵敏和选择性光学识别中的应用。

相似文献

1
Functional cyclophanes: promising hosts for optical biomolecular recognition.功能环芳烷:用于光学生物分子识别的有前途的主体。
Chem Soc Rev. 2010 Nov;39(11):4158-68. doi: 10.1039/b920032k. Epub 2010 Aug 20.
2
Molecular "light switch" for G-quadruplexes and i-motif of human telomeric DNA: [Ru(phen)2(dppz)]2+.用于人端粒 DNA 的 G-四链体和 i- 回文结构的分子“光开关”:[Ru(phen)2(dppz)]2+。
Dalton Trans. 2010 Mar 14;39(10):2490-3. doi: 10.1039/b916094a. Epub 2010 Jan 22.
3
Differentiating quadruplexes: binding preferences of a luminescent dinuclear ruthenium(II) complex with four-stranded DNA structures.区分四联体:具有四条链 DNA 结构的发光双核钌(II)配合物的结合偏好。
Org Biomol Chem. 2010 Jun 7;8(11):2617-21. doi: 10.1039/b924263e. Epub 2010 Mar 29.
4
Characterization of nucleobase-amino acid stacking interactions utilized by a DNA repair enzyme.一种DNA修复酶所利用的核碱基-氨基酸堆积相互作用的表征
J Phys Chem B. 2006 Oct 5;110(39):19652-63. doi: 10.1021/jp061939v.
5
Tetrapeptides induce selective recognition for G-quadruplexes when conjugated to a DNA-binding platform.当与DNA结合平台偶联时,四肽可诱导对G-四链体的选择性识别。
Org Biomol Chem. 2004 Oct 21;2(20):2925-31. doi: 10.1039/B409698C. Epub 2004 Sep 20.
6
Molecular Pacman: folding, inclusion, and X-ray structures of tri- and tetraamino piperazine cyclophanes.分子“吃豆人”:三氨基和四氨基哌嗪环番的折叠、包合及X射线结构
Chemistry. 2008;14(11):3297-305. doi: 10.1002/chem.200701862.
7
Synthesis of mono-amino-functionalised ferrocene, ferrocene salts and ferrocenium salts.单氨基官能化二茂铁、二茂铁盐和二茂铁鎓盐的合成。
Dalton Trans. 2004 Feb 7(3):436-41. doi: 10.1039/b315359m. Epub 2003 Dec 22.
8
Stability and cations coordination of DNA and RNA 14-mer G-quadruplexes: a multiscale computational approach.DNA和RNA 14聚体G-四链体的稳定性及阳离子配位:一种多尺度计算方法。
J Phys Chem B. 2008 Sep 25;112(38):12115-23. doi: 10.1021/jp804036j. Epub 2008 Sep 3.
9
Interaction of [Ru(bpy)2(dppz)]2+ with human telomeric DNA: preferential binding to G-quadruplexes over i-motif.[Ru(bpy)2(dppz)]2+与人类端粒 DNA 的相互作用:优先与 G-四链体结合而不是 i- 型结构。
Biochimie. 2010 Apr;92(4):370-7. doi: 10.1016/j.biochi.2010.01.003. Epub 2010 Jan 21.
10
Bis-phenanthroline derivatives as suitable scaffolds for effective G-quadruplex recognition.双菲咯啉衍生物作为有效识别 G-四链体的合适支架。
Dalton Trans. 2010 Jul 7;39(25):5833-41. doi: 10.1039/c0dt00038h. Epub 2010 May 25.

引用本文的文献

1
Isothiourea-Catalysed Acylative Kinetic and Dynamic Kinetic Resolution of Planar Chiral Paracyclophanols.异硫脲催化的平面手性对环芳醇的酰基化动力学拆分和动态动力学拆分
Angew Chem Int Ed Engl. 2025 Jul 28;64(31):e202507126. doi: 10.1002/anie.202507126. Epub 2025 Jun 23.
2
Spherical Amides with Symmetry: Improved Synthetic Approach and Structural/Optical Analysis.具有对称性的球形酰胺:改进的合成方法及结构/光学分析
Molecules. 2025 Feb 26;30(5):1074. doi: 10.3390/molecules30051074.
3
Pd/NHC sequentially catalyzed atroposelective synthesis of planar-chiral macrocycles.
钯/氮杂环卡宾相继催化的平面手性大环化合物的对映选择性合成。
Chem Sci. 2024 Nov 4;15(46):19599-19603. doi: 10.1039/d4sc05482b. eCollection 2024 Nov 27.
4
N-Heterocyclic carbene-catalyzed enantioselective synthesis of planar-chiral cyclophanes via dynamic kinetic resolution.通过动态动力学拆分实现N-杂环卡宾催化的平面手性环芳的对映选择性合成。
Nat Commun. 2024 Mar 15;15(1):2338. doi: 10.1038/s41467-024-46376-8.
5
Remarkably Selective Binding, Behavior Modification, and Switchable Release of (Bipyridine)Ru(II) vis-à-vis (Phenanthroline)Ru(II) by Trimeric Cyclophanes in Water.三聚环芳烷在水中对(联吡啶)钌(II)相对于(菲咯啉)钌(II)的显著选择性结合、行为修饰及可切换释放
JACS Au. 2023 Jul 28;3(8):2257-2268. doi: 10.1021/jacsau.3c00279. eCollection 2023 Aug 28.
6
Stereoselective synthesis of [2.2]triphenylenophanes intramolecular double [2 + 2 + 2] cycloadditions.[2.2]三亚苯并环分子内双[2 + 2 + 2]环加成反应的立体选择性合成。
Chem Sci. 2023 Mar 10;14(15):3963-3972. doi: 10.1039/d3sc00571b. eCollection 2023 Apr 12.
7
Supramolecular Recognition of Cytidine Phosphate in Nucleotides and RNA Sequences.核苷酸和RNA序列中磷酸胞苷的超分子识别
JACS Au. 2023 Feb 13;3(3):964-977. doi: 10.1021/jacsau.2c00658. eCollection 2023 Mar 27.
8
Design and application of self-healable polymeric films and coatings for smart food packaging.用于智能食品包装的自修复聚合物薄膜和涂层的设计与应用
NPJ Sci Food. 2023 Mar 29;7(1):11. doi: 10.1038/s41538-023-00185-3.
9
Host-Guest Complexes.主体-客体配合物。
Int J Mol Sci. 2022 Dec 12;23(24):15730. doi: 10.3390/ijms232415730.
10
A Review of Crystalline Multibridged Cyclophane Cages: Synthesis, Their Conformational Behavior, and Properties.多桥联笼状晶体的综述:合成、构象行为和性质。
Molecules. 2022 Oct 20;27(20):7083. doi: 10.3390/molecules27207083.