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Organocatalytic asymmetric Michael addition of alpha-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters.有机催化不对称迈克尔加成反应：α-芳基环戊酮与硝基烯烃的反应，用于构建相邻的季碳和叔碳立体中心。

Chem Commun (Camb). 2010 Sep 28;46(36):6840-2. doi: 10.1039/c0cc01987a. Epub 2010 Aug 20.

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Asymmetric generation of fluorine-containing quaternary carbons adjacent to tertiary stereocenters: uses of fluorinated methines as nucleophiles.与叔立体中心相邻的含氟季碳的不对称生成：氟化次甲基作为亲核试剂的用途。

Chem Commun (Camb). 2009 Apr 21(15):2044-6. doi: 10.1039/b823184b. Epub 2009 Feb 26.

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Organocatalytic Asymmetric Michael Addition of Pyrazol-5-ones to β-Trifluoromethyl-α,β-unsaturated Ketones: Stereocontrolled Construction of Vicinal Quaternary and Tertiary Stereocenters.有机催化不对称迈克尔加成反应：吡唑-5-酮与β-三氟甲基-α,β-不饱和酮的反应，立体选择性构建毗邻的季碳和叔碳中心。

J Org Chem. 2020 Jan 17;85(2):574-584. doi: 10.1021/acs.joc.9b02676. Epub 2019 Dec 19.

4

Asymmetric Michael addition reaction of 3-substituted-N-Boc oxindoles to activated terminal alkenes catalyzed by a bifunctional tertiary-amine thiourea catalyst.双功能叔胺硫脲催化 3-取代-N-Boc 氧吲哚与活化末端烯烃的不对称迈克尔加成反应。

Org Biomol Chem. 2010 Jan 7;8(1):77-82. doi: 10.1039/b918644a. Epub 2009 Oct 29.

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Enantioselective synthesis of polysubstituted cyclopentanones by organocatalytic double Michael addition reactions.通过有机催化的双迈克尔加成反应对多取代环戊酮的对映选择性合成。

Org Lett. 2010 Aug 20;12(16):3634-7. doi: 10.1021/ol101414b.

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Catalytic enantioselective construction of quaternary stereocenters by direct vinylogous Michael addition of deconjugated butenolides to nitroolefins.通过去共轭丁烯内酯与硝基烯烃的直接 vinylogous Michael 加成反应，催化对映选择性构建季立体中心。

Chem Commun (Camb). 2012 May 25;48(42):5193-5. doi: 10.1039/c2cc31700a. Epub 2012 Apr 18.

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Asymmetric direct vinylogous Michael reaction of activated alkenes to nitroolefins catalyzed by modified cinchona alkaloids.修饰金鸡纳生物碱催化的活性烯烃与硝基烯烃的不对称直接乙烯型迈克尔反应。

Org Lett. 2005 Nov 10;7(23):5293-6. doi: 10.1021/ol052283b.

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Organocatalytic asymmetric tandem Michael-Henry reactions: a highly stereoselective synthesis of multifunctionalized cyclohexanes with two quaternary stereocenters.有机催化不对称串联迈克尔-亨利反应：具有两个季碳立体中心的多官能化环己烷的高立体选择性合成。

Org Lett. 2008 Jun 19;10(12):2437-40. doi: 10.1021/ol8007183. Epub 2008 May 20.

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Organocatalytic asymmetric synthesis of chiral fluorinated quaternary carbon containing beta-ketoesters.手性含氟季碳β-酮酯的有机催化不对称合成

Chem Commun (Camb). 2009 Apr 28(16):2136-8. doi: 10.1039/b900777f. Epub 2009 Mar 12.

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Asymmetric Assembly of All-Carbon Tertiary/Quaternary Nonadjacent Stereocenters through Organocatalytic Conjugate Addition of α-Cyanoacetates to a Methacrylate Equivalent.通过有机催化α-氰基乙酸酯与甲基丙烯酸酯类似物的共轭加成实现全碳叔/季非相邻立体中心的不对称组装。

Chemistry. 2016 Sep 12;22(38):13690-6. doi: 10.1002/chem.201603082. Epub 2016 Aug 3.

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有机催化不对称迈克尔加成反应：α-芳基环戊酮与硝基烯烃的反应，用于构建相邻的季碳和叔碳立体中心。

Organocatalytic asymmetric Michael addition of alpha-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters.

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