通过铑（I）催化的对映选择性反烯丙基化反应对中特-叔-降冰片烯醇进行去对称化。
Desymmetrizations of meso-tert-norbornenols by rhodium(I)-catalyzed enantioselective retro-allylations.
机构信息
Laboratory of Organic Chemistry, ETH Zurich, HCI H 304, Wolfgang-Pauli-Strasse 10, 8093 Zurich, Switzerland.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):346-8. doi: 10.1039/c0cc01950j. Epub 2010 Aug 31.
PMID:20820518
Abstract
Rhodium-catalyzed desymmetrizations of meso-tert-norbornenols by retro-allylations generate allyl-rhodium species that allow for a rich and diverse downstream reactivity.
摘要
铑催化的消旋特-叔-降冰片烯醇的反烯丙基化反应生成烯丙基-铑物种，允许丰富多样的下游反应性。
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