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2Fe2S-Fe(ii)(S-2N)(2)模型的合成、结构和电化学研究，用于[FeFe]-氢化酶的 H 簇。

Synthesis, structures and electrochemistry studies of 2Fe2S-Fe(ii)(S-2N)(2) models for H-cluster of [FeFe]-hydrogenase.

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, PR China.

出版信息

Dalton Trans. 2010 Oct 28;39(40):9484-6. doi: 10.1039/c0dt00505c. Epub 2010 Sep 8.

DOI:10.1039/c0dt00505c
PMID:20830399
Abstract

A series of model complexes (μ-pdt)Fe(2)(CO)(5)M(sip)(2) (M = Fe, Ni) were synthesized as H-cluster analogues of [FeFe]-hydrogenase. Their electrochemical behaviours were investigated and it is proposed that the bridging metal bis(tris-chelate) groups act as electron transfer sites in theses mimics.

摘要

一系列模型配合物 (μ-pdt)Fe(2)(CO)(5)M(sip)(2)（M = Fe，Ni）被合成作为 [FeFe]-氢化酶的 H 簇类似物。它们的电化学行为进行了研究，提出桥连金属双（三螯合）基团在这些模拟物中充当电子转移位点。

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