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对三所小学室内空气中挥发性有机化合物浓度及其健康风险的评估。

An assessment of indoor air concentrations and health risks of volatile organic compounds in three primary schools.

机构信息

İzmir Institute of Technology, Department of Chemical Engineering and Environmental Research Center, Gülbahçe, Urla 35430 İzmir, Turkey.

出版信息

Int J Hyg Environ Health. 2011 Jan;214(1):36-46. doi: 10.1016/j.ijheh.2010.08.008. Epub 2010 Sep 15.

Abstract

Concentrations of volatile organic compounds (VOCs), including formaldehyde, in classrooms, kindergartens, and outdoor playgrounds of three primary schools were measured in spring, winter, and fall terms in İzmir, Turkey. A health-risk assessment was conducted for odor detection, sensory irritation, chronic toxic effects, and cancer. Active sampling was applied for VOCs and formaldehyde on Tenax TA and DNPH tubes, respectively. VOCs were analyzed in a thermal desorption-GC-MS system. Formaldehyde analysis was performed using an HPLC instrument. Benzene, toluene, and formaldehyde were the most abundant compounds with 95th percentile indoor air concentrations of 29, 87, and 106 μg/m(3), respectively. Naphthalene and xylenes followed them with an order of magnitude lower concentrations. Two isomers of dichlorobenzene (1,3 and 1,4) were the other notable compounds. The concentrations were utilized to classify the indoor air pollutants with respect to potential health effects. In addition, carcinogenic and chronic toxic risks were estimated using Monte-Carlo simulation. Formaldehyde appears to be the most concerning pollutant with high chronic toxic and carcinogenic risk levels according to the health assessment followed by naphthalene, benzene, and toluene due to their chronic effects.

摘要

在土耳其伊兹密尔的三所小学的春季、冬季和秋季,对教室、幼儿园和户外操场的挥发性有机化合物(VOC)浓度(包括甲醛)进行了测量。对嗅觉探测、感官刺激、慢性毒性效应和癌症进行了健康风险评估。采用活性采样法分别在 Tenax TA 和 DNPH 管上对 VOC 和甲醛进行采样。采用热解吸-气相色谱-质谱系统分析 VOC,采用高效液相色谱仪分析甲醛。苯、甲苯和甲醛是最丰富的化合物,第 95 百分位数室内空气浓度分别为 29、87 和 106μg/m(3)。萘和二甲苯紧随其后,浓度低一个数量级。二氯苯(1,3 和 1,4)的两种异构体也是其他显著的化合物。利用这些浓度对室内空气污染物进行了分类,以评估它们对潜在健康影响的程度。此外,还使用蒙特卡罗模拟法对致癌和慢性毒性风险进行了评估。根据健康评估,甲醛似乎是最令人担忧的污染物,具有高慢性毒性和致癌风险水平,其次是萘、苯和甲苯,因为它们具有慢性效应。

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