黄素-环糊精缀合物作为在水相介质中用过氧化氢进行对映选择性亚砜化的催化剂。
Flavin-cyclodextrin conjugates as catalysts of enantioselective sulfoxidations with hydrogen peroxide in aqueous media.
机构信息
Department of Organic Chemistry, Institute of Chemical Technology, Prague, Technická 5, Prague 6, Czech Republic.
出版信息
Chem Commun (Camb). 2010 Oct 28;46(40):7599-601. doi: 10.1039/c0cc02562c. Epub 2010 Sep 10.
PMID:20835467
Abstract
β-Cyclodextrin-flavin conjugates are highly efficient catalysts for the sulfoxidation of methyl phenyl sulfides with hydrogen peroxide in neat aqueous media operating at loadings down to 0.2 mol% and allowing for enantioselectivities up to 80% ee.
摘要
β-环糊精-黄素缀合物是在负载量低至 0.2 mol%、对映选择性高达 80%ee 的条件下，在 neat 水相介质中用双氧水高效催化甲基苯基硫醚氧化的催化剂。
Zotero 插件