Nisar Muhammad, Kaleem Waqar Ahmad, Adhikari Achyut, Ali Zulfiqar, Hussain Nusrat, Khan Inamullah, Qayum Mughal, Choudhary M Iqbal
Institute of Chemical Sciences, University of Peshwar, Peshwar-25120, Pakistan.
Nat Prod Commun. 2010 Aug;5(8):1205-8.
The structures of (3S,7R,13S)-6-[2-(dimethylamino)-3-phenylpropanoyl]-19-methoxy-2-oxa-6,9,15-triazatetracyclo[16.3.1.0(3,7). 0(9,13)]docosa-1-(22),16,18,20-tetraene-8,14-dione (1), nummularin-C (2) and nummularin-R (3) have been previously determined mainly based on mass spectrometric data. Stereochemistry and complete 1H and 13C NMR spectroscopic data assignments of these compounds are now described. Compounds 1 and 2 are reported for the first time from Zizyphus oxyphylla.
(3S,7R,13S)-6-[2-(二甲基氨基)-3-苯基丙酰基]-19-甲氧基-2-氧杂-6,9,15-三氮杂四环[16.3.1.0(3,7).0(9,13)]二十二碳-1-(22),16,18,20-四烯-8,14-二酮(1)、钱币菌素-C(2)和钱币菌素-R(3)的结构先前主要基于质谱数据确定。现在描述了这些化合物的立体化学以及完整的1H和13C NMR光谱数据归属。化合物1和2首次从尖叶枣中报道。