• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Catalytic hydrogen evolution from mononuclear iron(II) carbonyl complexes as minimal functional models of the [FeFe] hydrogenase active site.

作者信息

Kaur-Ghumaan Sandeep, Schwartz Lennart, Lomoth Reiner, Stein Matthias, Ott Sascha

机构信息

Department of Photochemistry and Molecular Science, Uppsala University, Box 523, 75120 Uppsala, Sweden.

出版信息

Angew Chem Int Ed Engl. 2010 Oct 18;49(43):8033-6. doi: 10.1002/anie.201002719.

DOI:10.1002/anie.201002719
PMID:20845342
Abstract
摘要

相似文献

1
Catalytic hydrogen evolution from mononuclear iron(II) carbonyl complexes as minimal functional models of the [FeFe] hydrogenase active site.单核铁（II）羰基配合物作为[FeFe]氢化酶活性位点的最小功能模型催化析氢反应。
Angew Chem Int Ed Engl. 2010 Oct 18;49(43):8033-6. doi: 10.1002/anie.201002719.
2
One- to two-electron reduction of an [FeFe]-hydrogenase active site mimic: the critical role of fluxionality of the [2Fe2S] core.[FeFe]氢化酶活性位点模拟物的单电子和双电子还原：[2Fe2S]核心的流动性的关键作用。
J Am Chem Soc. 2009 Aug 19;131(32):11290-1. doi: 10.1021/ja904520x.
3
Approaches to efficient molecular catalyst systems for photochemical H2 production using [FeFe]-hydrogenase active site mimics.用于光化学 H2 生产的 [FeFe]-氢化酶活性位点模拟物的高效分子催化剂体系的方法。
Dalton Trans. 2011 Dec 28;40(48):12793-800. doi: 10.1039/c1dt11166c. Epub 2011 Oct 10.
4
An iron carbonyl pyridonate complex related to the active site of the [Fe]-hydrogenase (Hmd).一种与[Fe] -氢化酶（Hmd）活性位点相关的羰基吡啶酸铁配合物。
Inorg Chem. 2009 Apr 20;48(8):3514-6. doi: 10.1021/ic900281g.
5
Resin-bound models of the [FeFe]-hydrogenase enzyme active site and studies of their reactivity.[铁铁]氢化酶活性位点的树脂结合模型及其反应性研究。
Dalton Trans. 2009 Jun 14(22):4344-50. doi: 10.1039/b823152d. Epub 2009 Mar 2.
6
High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site.由[FeFe]-氢化酶活性位点的模型配合物催化的高周转率光化学产氢反应。
Chemistry. 2010 Jan 4;16(1):60-3. doi: 10.1002/chem.200902489.
7
A carbonyl-rich bridging hydride complex relevant to the Fe-Fe hydrogenase active site.与 Fe-Fe 氢化酶活性位点相关的富羰基桥接氢化物配合物。
Inorg Chem. 2010 Nov 1;49(21):9746-8. doi: 10.1021/ic1017328.
8
An oxidized active site model for the FeFe hydrogenase: reduction with hydrogen gas.用于 FeFe 氢化酶的氧化活性位点模型：氢气还原。
Inorg Chem. 2011 Sep 5;50(17):7925-7. doi: 10.1021/ic2009573. Epub 2011 Jul 27.
9
DFT/TDDFT exploration of the potential energy surfaces of the ground state and excited states of Fe2(S2C3H6)(CO)6: a simple functional model of the [FeFe] hydrogenase active site.Fe2(S2C3H6)(CO)6基态和激发态势能面的密度泛函理论/含时密度泛函理论研究：[FeFe]氢化酶活性位点的一个简单函数模型
J Phys Chem A. 2009 May 14;113(19):5657-70. doi: 10.1021/jp809347h.
10
Electrocatalytic dihydrogen evolution mechanism of [Fe2(CO)4(kappa(2)-Ph2PCH2CH2PPh2)(mu-S(CH2)3S)] and related models of the [FeFe]-hydrogenases active site: a DFT investigation.[Fe2(CO)4(kappa(2)-Ph2PCH2CH2PPh2)(mu-S(CH2)3S)]电催化双氢析出机制及相关 [FeFe]-氢化酶活性位点模型的理论研究。
Dalton Trans. 2010 Aug 21;39(31):7320-9. doi: 10.1039/b926040d. Epub 2010 Jul 1.

引用本文的文献

1
Mononuclear manganese complexes as hydrogen evolving catalysts.单核锰配合物作为析氢催化剂。
Front Chem. 2022 Oct 7;10:993085. doi: 10.3389/fchem.2022.993085. eCollection 2022.
2
Remarkable Enhancement of Catalytic Activity of Cu-Complexes in the Electrochemical Hydrogen Evolution Reaction by Using Triply Fused Porphyrin.三重融合卟啉显著增强铜配合物在电化学析氢反应中的催化活性。
ChemSusChem. 2023 Jan 9;16(1):e202201146. doi: 10.1002/cssc.202201146. Epub 2022 Dec 14.
3
Heterodinuclear nickel(ii)-iron(ii) azadithiolates as structural and functional models for the active site of [NiFe]-hydrogenases.
异双核镍（II）-铁（II）氮杂二硫醇盐作为[NiFe]氢化酶活性位点的结构和功能模型。
RSC Adv. 2020 Aug 28;10(53):32069-32077. doi: 10.1039/d0ra04344c. eCollection 2020 Aug 26.
4
Graphene Supported Rhodium Nanoparticles for Enhanced Electrocatalytic Hydrogen Evolution Reaction.用于增强电催化析氢反应的石墨烯负载铑纳米颗粒
Sci Rep. 2019 Nov 19;9(1):17027. doi: 10.1038/s41598-019-53501-x.
5
Electrocatalytic hydrogen evolution with gallium hydride and ligand-centered reduction.氢化镓的电催化析氢及配体中心还原反应
Chem Sci. 2018 Dec 27;10(8):2308-2314. doi: 10.1039/c8sc05247f. eCollection 2019 Feb 28.
6
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.利用第一行过渡金属配合物进行电驱动和太阳能驱动的燃料合成。
Chem Rev. 2019 Feb 27;119(4):2752-2875. doi: 10.1021/acs.chemrev.8b00392. Epub 2019 Feb 15.
7
FeS Cubane Type Cluster Immobilized on a Graphene Support: A High Performance H Evolution Catalysis in Acidic Water.固定在石墨烯载体上的立方烷型硫化铁簇：酸性水中的高性能析氢催化
Sci Rep. 2017 Dec 5;7(1):16948. doi: 10.1038/s41598-017-17121-7.
8
Enhancing H evolution performance of an immobilised cobalt catalyst by rational ligand design.通过合理的配体设计提高固定化钴催化剂的氢演化性能。
Chem Sci. 2015 May 1;6(5):2727-2736. doi: 10.1039/c4sc03946g. Epub 2015 Feb 2.
9
Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen-Evolution Reaction.单核镍卟啉与双核镍卟啉对质子还原的比较：氢原子转移反应的实验和理论证据。
Angew Chem Int Ed Engl. 2016 Apr 25;55(18):5457-62. doi: 10.1002/anie.201510001. Epub 2016 Mar 30.
10
Synthesis, Characterization, and Reactivity of Functionalized Trinuclear Iron-Sulfur Clusters - A New Class of Bioinspired Hydrogenase Models.功能化三核铁硫簇合物的合成、表征及反应活性——一类新型的仿生氢化酶模型
Eur J Inorg Chem. 2015 Sep;2015(25):4199-4206. doi: 10.1002/ejic.201500574. Epub 2015 Aug 7.