Department of Civil Engineering, National University of Singapore, Singapore, Singapore.
Water Res. 2011 Jan;45(2):705-13. doi: 10.1016/j.watres.2010.08.035. Epub 2010 Aug 27.
Three 6-L submerged anaerobic membrane bioreactors (SAnMBRs) with solids retention times (SRTs) of 30, 60 and infinite days were setup for treating synthetic low-strength wastewater at hydraulic retention times (HRTs) of 12, 10 and 8 h. Total COD removal efficiencies higher than 97% were achieved at all operating conditions. Maximum biogas production rate was 0.056 L CH(4)/g MLVSS d at an infinite SRT. A shorter HRT or longer SRT increased biogas production due to increased organic loading rate or enhanced dominancy of methanogenics. A decrease in HRT enhanced growth of biomass and accumulation of soluble microbial products (SMP), which accelerated membrane fouling. A drop in carbohydrate to protein ratio also inversely affected fouling. At 12-h HRT, the effect of SRT on biomass concentration in SAnMBRs was negligible and membrane fouling was controlled by variant surface modification due to different SMP compositions, i.e., higher carbohydrate and protein concentrations in SMP at longer SRT resulted in higher membrane fouling rate. At 8 and 10-h HRTs, infinite SRT in SAnMBR caused highest MLSS and SMP concentrations, which sped up particle deposition and biocake/biofilm development. At longer SRT, lower extracellular polymeric substances reduced flocculation of particulates and particle sizes, further aggravated membrane fouling.
三个水力停留时间(HRT)分别为 12、10 和 8 小时,固体停留时间(SRT)分别为 30、60 和无限天的 6-L 淹没式厌氧膜生物反应器(SAnMBR)被用于处理低浓度合成废水。在所有运行条件下,总 COD 去除效率均高于 97%。在无限 SRT 时,最大沼气产率为 0.056 L CH(4)/g MLVSS d。较短的 HRT 或较长的 SRT 会由于增加有机负荷率或增强产甲烷菌的优势而增加沼气产量。HRT 的降低会促进生物量的生长和可溶性微生物产物(SMP)的积累,从而加速膜污染。碳水化合物与蛋白质比例的降低也会对污染产生不利影响。在 HRT 为 12 小时的情况下,SRT 对 SAnMBR 中生物质浓度的影响可以忽略不计,膜污染是由不同 SMP 组成引起的可变表面改性控制的,即较长 SRT 下 SMP 中的碳水化合物和蛋白质浓度较高,导致更高的膜污染速率。在 HRT 为 8 和 10 小时的情况下,SAnMBR 中的无限 SRT 会导致最高的 MLSS 和 SMP 浓度,从而加速颗粒沉积和生物膜/生物膜的发展。在较长的 SRT 下,较低的胞外聚合物物质减少了颗粒的絮凝和颗粒尺寸,进一步加剧了膜污染。