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病毒模板化金属纳米颗粒。

Virus templated metallic nanoparticles.

机构信息

Department of Biological Chemistry, John Innes Centre, Norwich Research Park, Colney, Norwich, NR4 7UH, UK.

出版信息

Nanoscale. 2010 Dec;2(12):2596-600. doi: 10.1039/c0nr00525h. Epub 2010 Sep 28.

Abstract

Plant viruses are considered as nanobuilding blocks that can be used as synthons or templates for novel materials. Cowpea mosaic virus (CPMV) particles have been shown to template the fabrication of metallic nanoparticles by an electroless deposition metallization process. Palladium ions were electrostatically bound to the virus capsid and, when reduced, acted as nucleation sites for the subsequent metal deposition from solution. The method, although simple, produced highly monodisperse metallic nanoparticles with a diameter of ca. ≤35 nm. CPMV-templated particles were prepared with cobalt, nickel, iron, platinum, cobalt-platinum and nickel-iron.

摘要

植物病毒被认为是纳米构建块,可以用作新型材料的缩合剂或模板。豇豆花叶病毒(CPMV)颗粒已被证明可以通过无电沉积金属化过程模板化制造金属纳米粒子。钯离子通过静电结合到病毒衣壳上,并且在被还原时,作为随后从溶液中沉积金属的成核位点。该方法虽然简单,但却产生了高度单分散的金属纳米粒子,其直径约为≤35nm。使用钴、镍、铁、铂、钴-铂和镍-铁制备了 CPMV 模板化颗粒。

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