Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Bioresour Technol. 2011 Jan;102(2):1095-102. doi: 10.1016/j.biortech.2010.08.076. Epub 2010 Aug 26.
In this study, a novel continuous reactor has been developed to produce high quality methyl esters (biodiesel) from palm oil. A microporous TiO2/Al2O3 membrane was packed with potassium hydroxide catalyst supported on palm shell activated carbon. The central composite design (CCD) of response surface methodology (RSM) was employed to investigate the effects of reaction temperature, catalyst amount and cross flow circulation velocity on the production of biodiesel in the packed bed membrane reactor. The highest conversion of palm oil to biodiesel in the reactor was obtained at 70 °C employing 157.04 g catalyst per unit volume of the reactor and 0.21 cm/s cross flow circulation velocity. The physical and chemical properties of the produced biodiesel were determined and compared with the standard specifications. High quality palm oil biodiesel was produced by combination of heterogeneous alkali transesterification and separation processes in the packed bed membrane reactor.
在这项研究中,开发了一种新型连续式反应器,用于从棕榈油中生产高质量的甲酯(生物柴油)。将微孔 TiO2/Al2O3 膜填充有负载在棕榈壳活性炭上的氢氧化钾催化剂。采用响应面法(RSM)的中心复合设计(CCD)研究了反应温度、催化剂用量和错流循环流速对填充床膜反应器中生物柴油生产的影响。在反应器中,在 70°C 下使用每单位反应器体积 157.04g 催化剂和 0.21cm/s 的错流循环流速,可获得最高的棕榈油转化率为生物柴油。测定了所制备的生物柴油的物理和化学性质,并与标准规格进行了比较。在填充床膜反应器中,通过非均相堿酯交换和分离过程的结合,生产出了高质量的棕榈油生物柴油。