Kano H, Kawata S
Appl Opt. 1994 Aug 1;33(22):5166-70. doi: 10.1364/AO.33.005166.
A method to enhance the absorption sensitivity of a sample by utilizing surface-field enhancement with surface-plasmon resonance is proposed. The experimental setup is based on the configuration for the attenuated total internal reflection (ATR) method but with a thin metal film deposed on the substrate prism. The mechanism responsible for the sensitivity enhancement is analyzed theoretically; the best thickness for the metal film to have to attain optimum enhancement is numerically calculated. Experimental results are shown in which the proposed method compared with the conventional ATR method exhibits the sensitivity enhancement of the absorption measurement. The sensor applications for this technique are also discussed.
提出了一种利用表面等离子体共振的表面场增强来提高样品吸收灵敏度的方法。实验装置基于衰减全内反射(ATR)方法的配置,但在基底棱镜上沉积了一层薄金属膜。从理论上分析了灵敏度提高的机制;通过数值计算得出了金属膜达到最佳增强效果所需的最佳厚度。给出了实验结果,其中将所提出的方法与传统的ATR方法进行比较,展示了吸收测量的灵敏度提高。还讨论了该技术的传感器应用。