Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology, Ulsan, 689-805, South Korea.
Chem Commun (Camb). 2010 Dec 14;46(46):8788-90. doi: 10.1039/c0cc03808c. Epub 2010 Oct 19.
Redox couples based on cobalt complexes were found to be effective in regenerating both inorganic CdSe quantum dot- and organic dye-sensitizers. The hybrid sensitizer composed of CdSe QD and ruthenium sensitizer (Z907Na) dye showed a maximum power conversion efficiency of 4.76% on using cobalt(o-phen)(3)(2+/3+) as a common redox mediator.
基于钴配合物的氧化还原偶联物被发现能有效地再生无机 CdSe 量子点和有机染料敏化剂。由 CdSe QD 和钌敏化剂 (Z907Na) 染料组成的混合敏化剂在使用钴(o-phen)(3)(2+/3+)作为常见的氧化还原介体时,最大的功率转换效率为 4.76%。