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随机多属性分析在单壁碳纳米管合成过程评估中的应用。

Application of stochastic multiattribute analysis to assessment of single walled carbon nanotube synthesis processes.

机构信息

U.S. Army Corps of Engineers, Engineer Research and Development Center, Concord, Massachusetts 01742, USA.

出版信息

Environ Sci Technol. 2010 Nov 15;44(22):8704-11. doi: 10.1021/es102117k. Epub 2010 Oct 22.

DOI:10.1021/es102117k
PMID:20964398
Abstract

The unprecedented uncertainty associated with engineered nanomaterials greatly expands the need for research regarding their potential environmental consequences. However, decision-makers such as regulatory agencies, product developers, or other nanotechnology stakeholders may not find the results of such research directly informative of decisions intended to mitigate environmental risks. To help interpret research findings and prioritize new research needs, there is an acute need for structured decision-analytic aids that are operable in a context of extraordinary uncertainty. Whereas existing stochastic decision-analytic techniques explore uncertainty only in decision-maker preference information, this paper extends model uncertainty to technology performance. As an illustrative example, the framework is applied to the case of single-wall carbon nanotubes. Four different synthesis processes (arc, high pressure carbon monoxide, chemical vapor deposition, and laser) are compared based on five salient performance criteria. A probabilistic rank ordering of preferred processes is determined using outranking normalization and a linear-weighted sum for different weighting scenarios including completely unknown weights and four fixed-weight sets representing hypothetical stakeholder views. No single process pathway dominates under all weight scenarios, but it is likely that some inferior process technologies could be identified as low priorities for further research.

摘要

与工程纳米材料相关的前所未有的不确定性极大地增加了对其潜在环境后果进行研究的必要性。然而,决策者(如监管机构、产品开发商或其他纳米技术利益相关者)可能不会发现此类研究的结果直接有助于减轻环境风险的决策。为了帮助解释研究结果并确定新的研究需求的优先级,迫切需要在非常不确定的情况下可操作的结构化决策分析辅助工具。虽然现有的随机决策分析技术仅在决策者偏好信息中探索不确定性,但本文将技术性能的模型不确定性扩展到其中。作为一个说明性示例,该框架应用于单壁碳纳米管的情况。基于五个突出的性能标准,对四种不同的合成工艺(电弧、高压一氧化碳、化学气相沉积和激光)进行了比较。使用超越归一化和线性加权和确定首选工艺的概率等级排序,对于不同的加权方案,包括完全未知的权重和代表假设的利益相关者观点的四个固定权重集。在所有权重方案下,没有单个工艺途径占主导地位,但很可能会确定一些较差的工艺技术作为进一步研究的低优先级。

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